Methods of fabricating substrates

This patent resulted from a continuation application of U.S. patent application Ser. No. 12/328,435, filed Dec. 4, 2008, entitled “Methods of Fabricating Substrates”, naming Scott Sills, Gurtej S. Sandhu, and Anton deVilliers as inventors, the disclosure of which is incorporated by reference.

Embodiments disclosed herein pertain to methods of fabricating substrates, for example as may be used in the fabrication of integrated circuitry.

Integrated circuits are typically formed on a semiconductor substrate such as a silicon wafer or other semiconducting material. In general, layers of various materials which are either semiconducting, conducting or insulating are utilized to form the integrated circuits. By way of example, the various materials are doped, ion implanted, deposited, etched, grown, etc. using various processes. A continuing goal in semiconductor processing is to continue to strive to reduce the size of individual electronic components thereby enabling smaller and denser integrated circuitry.

One technique for patterning and processing semiconductor substrates is photolithography. Such includes deposition of a patternable masking layer commonly known as photoresist. Such materials can be processed to modify their solubility in certain solvents, and are thereby readily usable to form patterns on a substrate. For example, portions of a photoresist layer can be exposed to actinic energy through openings in a radiation-patterning tool, such as a mask or reticle, to change the solvent solubility of the exposed regions versus the unexposed regions compared to the solubility in the as-deposited state. Thereafter, the exposed or unexposed regions can be removed, depending on the type of photoresist, thereby leaving a masking pattern of the photoresist on the substrate. Adjacent areas of the underlying substrate next to the masked portions can be processed, for example by etching or ion implanting, to effect the desired processing of the substrate adjacent the masking material. In certain instances, multiple different layers of photoresist and/or a combination of photoresists with non-radiation sensitive masking materials are utilized.

The continual reduction in feature sizes places ever greater demands on the techniques used to form the features. For example, photolithography is commonly used to form patterned features, such as conductive lines. A concept commonly referred to as “pitch” can be used to describe the sizes of the features in conjunction with spaces immediately adjacent thereto. Pitch may be defined as the distance between an identical point in two neighboring features of a repeating pattern in a straight line cross section, thereby including the maximum width of the feature and the space to the next immediately adjacent feature. However, due to factors such as optics and light or radiation wave length, photolithography techniques tend to have a minimum pitch below which a particular photolithographic technique cannot reliably form features. Thus, minimum pitch of a photolithographic technique is an obstacle to continued feature size reduction using photolithography.

Pitch doubling or pitch multiplication is one proposed method for extending the capabilities of photolithographic techniques beyond their minimum pitch. Such typically forms features narrower than minimum photolithography resolution by depositing spacer-forming layers to have a lateral thickness which is less than that of the minimum capable photolithographic feature size. The spacer-forming layers are commonly anisotropically etched to form sub-lithographic features, and then the features which were formed at the minimum photolithographic feature size are etched from the substrate.

Using such technique where pitch is actually halved, such reduction in pitch is conventionally referred to as pitch “doubling”. More generally, “pitch multiplication” encompasses increase in pitch of two or more times and also of fractional values other than integers. Thus, conventionally, “multiplication” of pitch by a certain factor actually involves reducing the pitch by that factor.

FIG. 1 is a diagrammatic sectional view of a substrate in process in accordance with an embodiment of the invention.

FIG. 2 is a view of the FIG. 1 substrate at a processing step prior to that of FIG. 1 .

FIG. 3 is a view of the FIG. 1 substrate at a processing step subsequent to that shown by FIG. 1 .

FIG. 4 is a view of the FIG. 3 substrate at a processing step subsequent to that shown by FIG. 3 .

FIG. 5 is a view of the FIG. 4 substrate at a processing step subsequent to that shown by FIG. 4 .

FIG. 6 is a view of the FIG. 5 substrate at a processing step subsequent to that shown by FIG. 5 .

FIG. 7 is a view of the FIG. 6 substrate at a processing step subsequent to that shown by FIG. 6 .

FIG. 8 is a view of the FIG. 7 substrate at a processing step subsequent to that shown by FIG. 7 .

FIG. 9 is a view of the FIG. 8 substrate at a processing step subsequent to that shown by FIG. 8 .

FIG. 10 is a view of the FIG. 9 substrate at a processing step subsequent to that shown by FIG. 9 .

FIG. 11 is a diagrammatic sectional view of another substrate in process in accordance with an embodiment of the invention.

FIG. 12 is a view of the FIG. 11 substrate at a processing step subsequent to that shown by FIG. 11 .

FIG. 13 is a view of the FIG. 12 substrate at a processing step subsequent to that shown by FIG. 12 .

FIG. 14 is a view of the FIG. 13 substrate at a processing step subsequent to that shown by FIG. 13 .

FIG. 15 is a view of the FIG. 14 substrate at a processing step subsequent to that shown by FIG. 14 .

FIG. 16 is a view of the FIG. 15 substrate at a processing step subsequent to that shown by FIG. 15 .

FIG. 17 is a diagrammatic sectional view of another substrate in process in accordance with an embodiment of the invention.

FIG. 18 is a view of the FIG. 17 substrate at a processing step subsequent to that shown by FIG. 17 .

FIG. 19 is a view of the FIG. 18 substrate at a processing step subsequent to that shown by FIG. 18 .

FIG. 20 is a view of the FIG. 19 substrate at a processing step subsequent to that shown by FIG. 19 .

FIG. 21 is a view of the FIG. 20 substrate at a processing step subsequent to that shown by FIG. 20 .

FIG. 22 is a view of the FIG. 21 substrate at a processing step subsequent to that shown by FIG. 21 .

FIG. 23 is a diagrammatic sectional view of another substrate in process in accordance with an embodiment of the invention.

FIG. 24 is a view of the FIG. 23 substrate at a processing step subsequent to that shown by FIG. 23 .

FIG. 25 is a view of the FIG. 24 substrate at a processing step subsequent to that shown by FIG. 24 .

FIG. 26 is a view of the FIG. 25 substrate at a processing step subsequent to that shown by FIG. 25 .

FIG. 27 is a view of the FIG. 26 substrate at a processing step subsequent to that shown by FIG. 26 .

FIG. 28 is a view of the FIG. 27 substrate at a processing step subsequent to that shown by FIG. 27 .

FIG. 29 is a view of the FIG. 28 substrate at a processing step subsequent to that shown by FIG. 28 .

FIG. 30 is a view of the FIG. 29 substrate at a processing step subsequent to that shown by FIG. 29 .

FIG. 31 is a view of the FIG. 30 substrate at a processing step subsequent to that shown by FIG. 30 .

FIG. 32 is a diagrammatic sectional view of another substrate in process in accordance with an embodiment of the invention.

FIG. 33 is a view of the FIG. 32 substrate at a processing step subsequent to that shown by FIG. 32 .

FIG. 34 is a view of the FIG. 33 substrate at a processing step subsequent to that shown by FIG. 33 .

FIG. 35 is a view of the FIG. 34 substrate at a processing step subsequent to that shown by FIG. 34 .

FIG. 36 is a view of the FIG. 35 substrate at a processing step subsequent to that shown by FIG. 35 .

FIG. 37 is a view of the FIG. 36 substrate at a processing step subsequent to that shown by FIG. 36 .

Some embodiments of methods of fabricating a substrate in accordance with the invention, for example in forming integrated circuitry, are described initially with reference to FIGS. 1-10 . Referring to FIG. 1 , a substrate, for example a semiconductor substrate, is indicated generally with reference numeral 10 . In the context of this document, the term “semiconductor substrate” or “semiconductive substrate” is defined to mean any construction comprising semiconductive material, including, but not limited to, bulk semiconductive materials such as a semiconductive wafer (either alone or in assemblies comprising other materials thereon), and semiconductive material layers (either alone or in assemblies comprising other materials). The term “substrate” refers to any supporting structure, including, but not limited to, the semiconductive substrates described above.

Substrate 10 is depicted as comprising material 12 which will ultimately be processed through a mask pattern formed thereover. Material 12 may be homogenous or non-homogenous, for example comprising multiple different composition regions and/or layers. Spaced first features 14 have been formed over substrate 12 . Any suitable material is contemplated, and whether homogenous or non-homogenous. In the context of this document, “spaced” refers to the lateral direction as opposed to vertically or otherwise. Spaced first features 14 may be patterned/formed by any existing or yet-to-be-developed manner, with photolithographic patterning using photoresist (whether positive, negative or dual-tone resist resulting from single or multi-pattern lithography) being an example. Further, spaced first features 14 may be formed by any technique described below. In one example, spaced first features 14 may be in the form of elongated lines, for example running parallel one another over at least some portion of the substrate as would be viewed in a top-down view (not shown).

Further in one embodiment, spaced first features 14 may result from lateral etching/trimming of wider features. For example, FIG. 2 depicts substrate 10 at a processing step prior to that of FIG. 1 . Such is shown as comprising spaced mask features 16 , for example comprising, consisting essentially of, or consisting of photoresist, having been fabricated over substrate 12 in a repeating pattern of a pitch “P”. Pitch P may be equal to, greater than, or less than the minimum photolithographic resolution with which substrate 10 is fabricated. Regardless, spaced mask features 16 of FIG. 2 have been laterally trimmed to reduce their respective widths to produce the example construction of FIG. 1 which comprises spaced first features 14 . Such may be conducted by an isotropic etch which removes material approximately equally from the sides and tops of spaced mask features 16 . Alternately, chemistries and conditions may be used which tend to etch greater material from the lateral sides of spaced mask features 16 than from the respective tops. Alternately, chemistries and conditions may be used which tend to etch greater material from the tops of spaced mask features 16 than from the lateral sides.

For example, the construction depicted by FIG. 1 can be derived by plasma etching the substrate of FIG. 2 within an inductively coupled reactor. Example etching parameters which will achieve essentially isotropic etching where material of spaced mask features 16 is photoresist and/or other organic-comprising material are pressure from about 2 mTorr to about 50 mTorr, substrate temperature from about 0° C. to about 110° C., source power from about 150 watts to about 500 watts, and bias voltage at less than or equal to about 25 volts. An example etching gas is a combination of Cl 2 from about 20 sccm to about 100 sccm and O 2 from about 10 sccm to about 50 sccm. Where material of spaced mask features 16 comprises photoresist, such will isotropically etch mask features 16 at a rate from about 0.2 nanometer per second to about 3 nanometers per second. While such an example etch is essentially isotropic, greater lateral etching of the spaced mask features will occur as two sides are laterally exposed as compared to only a single upper surface thereof.

If even more lateral etching is desired in comparison to vertical etching, example parameter ranges in an inductively coupled reactor include pressure from about 2 mTorr to about 20 mTorr, source power from about 150 watts to about 500 watts, bias voltage at less than or equal to about 25 volts, substrate temperature of from about 0° C. to about 110° C., Cl 2 and/or HBr flow from about 20 sccm to about 100 sccm, O 2 flow from about 5 sccm to about 20 sccm, and CF 4 flow from about 80 sccm to about 120 sccm.

It may be desired that the stated etching provide greater removal from the top of the spaced mask features than from the sides, for example to either achieve equal elevation and width reduction or more elevation than width reduction. The example parameters for achieving greater etch rate in the vertical direction as opposed to the lateral direction include pressure from about 2 mTorr to about 20 mTorr, temperature from about 0° C. to about 100° C., source power from about 150 watts to about 300 watts, bias voltage at greater than or equal to about 200 volts, Cl 2 and/or HBr flow from about 20 sccm to about 100 sccm, and O 2 flow from about 10 sccm to about 20 sccm.

The example FIGS. 1 and 2 embodiments depict the respective features as having equal shapes and widths relative one another in the depicted cross section, as well as equal spacing therebetween. Such is not, however, required in this or other embodiments.

Referring to FIG. 3 , a material 18 has been deposited as part of substrate 10 , and from which anisotropically etched spacers will be formed. Such may be etchably different from the material of spaced first features 14 , and may be conductive, semiconductive or insulative, including any combination thereof. Examples include silicon dioxide, silicon nitride, organic antireflective coatings, inorganic antireflective coatings, polysilicon, titanium or titanium nitride, including any combination thereof. Referring to FIG. 4 , material 18 has been anisotropically etched to form spacers 20 on sidewalls of spaced first features 14 .

Referring to FIG. 5 , spaced first features 14 (not shown) have been removed from substrate 10 to form spaced second features which comprise spacers 20 . Where, for example, the material of spaced first features 14 comprised photoresist and/or other organic material, O 2 plasma etching will remove material 14 from between spacers 20 . Regardless, the removal of material 14 may or may not etch some of spacers 20 , with negligible such removal being shown in FIG. 5 to form spaced second features 20 . FIGS. 1 and 4 depict one example embodiment wherein first features 14 are equally spaced from each adjacent of the first features ( FIG. 1 ), and second features 20 are not equally spaced from each adjacent of the second features. Alternate embodiments are contemplated. For example and by way of example only, first features 14 may be equally spaced from each adjacent of the first features and second features 20 may be equally spaced from each adjacent of the second features. For purposes of the continuing discussion, FIG. 5 depicts respective closest pairs 21 of two immediately adjacent of second features 20 having a respective space between each two of a pair 21 .

Referring to FIG. 6 , a first material 22 has been deposited over spaced second features 20 , and may be of some different composition from that of spaced second features 20 . Material 22 may or may not be homogenous. Example materials include any of those described above for spacer-forming material 18 . In the FIG. 6 embodiment, first material 22 has a non-planar outermost surface 23 , and has been deposited to completely fill space between closest pairs 21 of two immediately adjacent of second features 20 .

Referring to FIG. 7 , a second material 24 has been deposited over first material 23 , and is of some different composition from that of first material 22 and from that of spaced second features 20 . Second material 24 has a planar outermost surface 25 . Such may, for example, result from the inherent deposition of material 24 in a liquid-fill manner, or from deposition of one or more conformal layers followed by some sort of polish-back or etch-back thereof. Example second materials 24 include photoresist and other polymers, for example polystyrene, polymethylmethacrylate and polysiloxane. Material 24 may or may not be homogenous.

Referring to FIG. 8 , only a portion of second material 24 has been removed to expose first material 22 and form regions of spaced second material 30 received over first material 22 . Any suitable etching technique and conditions can be selected by the artisan. Some of material 22 may or may not be etched during the processing to produce the construction of FIG. 8 .

Referring to FIG. 9 , first material 22 has been etched from between spaced second material 30 and spaced third features 32 have been formed which comprise spaced second material 30 received over first material 22 . Third features 32 are spaced from second features 20 . Any suitable substantially anisotropic etching chemistry and conditions can be selected by the artisan for producing the FIG. 9 construction. FIG. 9 depicts one example embodiment where a mask pattern 35 has been formed over substrate 12 and which comprises spaced second features 20 and spaced third features 32 . Such also depicts an example embodiment wherein pairs 21 of immediately adjacent spaced second features 20 alternate with individual of spaced third features 32 .

The above processing may be conducted, for example, to result in a pitch multiplication which may or may not be sub-lithographic. Regardless, the FIGS. 1-9 embodiments depict mask pattern 35 ( FIG. 9 ) having been formed to have a pitch which is one-third (an integer factor of 3) that of pitch “P” of spaced mask features 16 in FIG. 2 . Any degree of pitch reduction (including non-integer fractional reduction) in FIGS. 1-9 , or otherwise, will of course be in large part determined on the degree of any lateral trimming that may occur of spaced features (for example in forming the substrate of FIG. 2 from that of FIG. 1 ) in combination with thickness of the deposited layers to produce the features and the spaces between features. For example, the deposition thickness of material 18 in FIG. 3 in combination with the etching technique to produce FIG. 4 impacts the width of spaced second features 20 . Similarly, the deposition thickness of first material 22 in significant part determines spacing between second features 20 and third features 32 . Further and regardless, some or all of spaced second features 20 and/or spaced third features 32 may be further laterally trimmed after forming the FIG. 9 construction. Further by way of example, spaced second features 20 of FIG. 4 and/or FIG. 5 may be laterally trimmed.

The mask pattern comprising the spaced second features and the spaced third features is used to process the substrate received elevationally there-below through such mask pattern. Such processing may constitute any existing or yet-to-be developed technique, with etching and/or ion implanting being specific examples. FIG. 10 depicts one example with such processing wherein mask pattern 35 has been used as an etch mask while etching into material 12 of substrate 10 .

Additional embodiments are next described with reference to FIGS. 11-16 . FIG. 11 depicts an alternate embodiment substrate fragment 10 a corresponding in processing sequence to that of FIG. 6 . Like numerals from the first described embodiments have been utilized where appropriate, with construction differences being indicated with the suffix “a” or with different numerals. While the suffix “a” indicates different construction, example material for such constructions is the same as used in the above embodiments for the same numerals without the suffix “a”. In FIG. 11 , first material 22 a has been deposited much thinner than that depicted by deposition of material 22 in FIG. 6 to less than completely fill space between closest pairs 21 of two immediately adjacent of second features 20 .

Referring to FIG. 12 , second material 24 a has been formed over first material 22 a . FIGS. 11 and 12 depict one embodiment wherein first material 22 a has been deposited to a minimum thickness T which is less than that of second material 24 and less than maximum width of spaced second features 20 .

Referring to FIG. 13 , only a portion of second material 24 a has been removed to expose first material 22 a and form spaced second material 30 a received over first material 22 a.

Referring to FIG. 14 , first material 22 a has been etched from between spaced second material 30 a and third spaced features 32 a have been formed which comprise spaced second material 30 a received over first material 22 a . Third features 32 a are spaced from second features 20 . Accordingly, FIG. 14 depicts an example mask pattern 35 a having one of third features 32 a received between each of adjacent of second features 20 . Substrate 12 may be processed through the mask pattern 35 a of FIG. 14 which comprises spaced second features 20 and spaced third features 32 a , for example by etching, ion implanting, and/or other processes as described above. In FIG. 14 , spaced third features 32 a in mask pattern 35 a are not of the same size/shape.

FIG. 15 depicts additional processing of substrate 10 a to produce a mask pattern 35 aa . Such may be formed by laterally trimming width of third features 32 a after the etching of first material 22 a of FIG. 14 . In one embodiment after forming the third features, all of only some of the third features may be removed to form the mask pattern prior to processing substrate material there-below. For example, FIG. 15 depicts lateral trimming the third features 32 a which are received between the furthest spaced of second features 20 which has also resulted in complete removal of third features 32 a which were received between closest pairs 21 of adjacent second features 20 .

Referring to FIG. 16 , substrate 10 a has been processed through mask pattern 35 aa . The example processing depicted in FIG. 16 is that of ion implantation, forming implanted regions 36 .

An embodiment of the invention encompasses a method of fabricating a substrate which includes forming first and second spaced features over a substrate. For example, features 32 a in FIG. 14 may be considered as spaced first features, and features 20 in FIG. 14 may be considered as spaced second features. The first spaced features have elevationally outermost regions which are different in composition from elevationally outermost regions of the second spaced features. The first and second spaced features alternate with one another. By way of example only, FIG. 14 depicts such a construction where spaced features 32 a are considered as first spaced features and spaced features 20 are considered as second spaced features. Regardless, the second features may or may not be homogenous. In one embodiment, the first features comprise a second material received over a different composition first material. In one embodiment, the second features are of a composition which is different from that of the first and second materials.

In one embodiment, every other first feature is removed from the substrate and pairs of immediately adjacent second features are formed which alternate with individual of remaining of the first features. By way of example only, FIG. 15 depicts such an embodiment, wherein pairs 21 of immediately adjacent second features 20 alternate with individual of remaining of features 32 a . In one embodiment, the removing comprises etching. For example, the processing in producing a substrate such as shown in FIG. 15 may occur by laterally etching the first and second materials selectively relative to second features 20 to remove every other first feature 32 a from substrate 10 a . Such has also reduced width of remaining of features 32 a , thereby forming pairs 21 of immediately adjacent second features 20 which alternate with individual of the remaining of features 32 a . Chemistries and conditions can be selected by the artisan to achieve such etching, with the above-described examples in producing the substrate of FIG. 1 from that of FIG. 2 being but examples. In one embodiment where for example the act of removing is by etching, no etch mask is received over features 32 a during the act of etching. In one embodiment, no etch mask is received anywhere over the substrate during such etching.

After the removing of every other first feature from the substrate, the substrate is processed through a mask pattern comprising the pairs of immediately adjacent second features which alternate with individual of the remaining of the first features. By way of example only, FIG. 16 depicts such example processing with respect to a mask pattern 35 aa.

Additional embodiments of methods of fabricating a substrate are next described with reference to FIGS. 17-22 with respect to a substrate fragment 10 b . Like numerals with respect to the above-described embodiments are utilized where appropriate, with differences in construction being indicated with the suffix “b” or with different numerals. While the suffix “b” indicates different construction, example material for such constructions is the same as used in the above embodiments for the same numerals without the suffix “b”. FIG. 17 depicts alternate processing to that of FIGS. 6 and 11 above, and wherein an alterable material 40 has been formed over spaced second features 20 . Alterable material 40 interacts selectively or uniformly with certain materials with which it forms an interface. Alterable material 40 may be cast onto a pre-patterned surface (for example as shown) and may be conformal or non-conformal. Casting via spin-casting, dip-casting, drop-casting, or similar, are examples. The alterable material will be altered with material from the spaced second features to form altered material on sidewalls of the spaced second features. The altered material may form spontaneously upon deposition of the alterable material, or be subsequently activated, for example via thermal, photonic, electronic, ionic (including acid-based chemistry) treatments, by way of examples only. Accordingly, the altering may occur during deposition and/or after deposition. In one embodiment, no altering occurs until after completion of the deposition of the alterable material. Further, the altering may be self-limiting in the case of a limiting reagent or equilibrium conditions, or kinetically arrested if reactants are in excess. Alterable material 40 may have a planar outermost surface or a non-planar outermost surface, with an example planar outermost surface 42 being depicted in FIG. 17 . Alterable material 40 may or may not be homogenous.

Material 40 may be similar to a class of materials available from Clariant International, Ltd. as so-called “AZ R” materials, such as the materials designated as AZ R200™, AZ R500™ and AZ R600™. The “AZ R” materials contain organic compositions which cross-link upon exposure to acid released from chemically-amplified resist. Accordingly for example, such materials constitute an example alterable material where material of spaced second features 20 comprises chemically-amplified resist. More specifically, an “AZ R” material may be coated across photoresist, and subsequently the resist may be baked at a temperature of from about 100° C. to about 120° C. to diffuse acid from the resist into the alterable material to form chemical cross-links within regions of the alterable material proximate the resist. Portions of the material adjacent the resist are thus selectively hardened relative to other portions of material that are not sufficiently proximate the resist. The material may then be exposed to conditions which selectively remove the non-hardened portions relative to the hardened portions. Such removal may be accomplished utilizing, for example, 10% isopropyl alcohol in deionized water, or a solution marketed as “SOLUTION C™” by Clariant International, Ltd. Processes utilizing the “AZ R” materials are sometimes considered examples of RELACS (Resolution Enhancement Lithography Assisted by Chemical Shrink) processes.

A challenge with the “AZ R” materials is that they can be similar enough in composition to photoresist that it may be difficult to selectively remove photoresist relative to hardened “AZ R” materials. In one embodiment, alterable material 40 may be similar to the “AZ R” materials in that it may comprise a similar or identical organic composition which is altered (for instance, forms cross-links) upon exposure to one or more substances (for instance, acid) released from material 20 over which material 40 lies when the substrate is baked. However, unlike “AZ R” materials, material 40 may also contain one or more components disbursed in the organic composition which are provided to chemically change material 40 relative to material of features 20 (for example, photoresist in embodiments where material of features 20 may be selectively removed relative to material 40 ). Components which may be disbursed in an organic composition of a material 40 may include one or more of titanium, carbon, fluorine, bromine, silicon and germanium. Any carbon disbursed in the organic composition may be part of a carbide compound so it is chemically different from bulk carbon of the organic composition. Any fluorine and/or bromine may be, for example, comprised of hydrofluoric acid and hydrobromic acid. In some embodiments, the components disbursed in an organic composition of a material 40 include one or more inorganic components, such as, for example, silicon, germanium, metals (for instance, titanium, tungsten, platinum, etc.) and/or metal-containing compounds (for instance, metal nitride, metal silicide, etc.). The component of material 40 that is similar to “AZ R” materials may be referred to as an “AZ R”-type composition. Accordingly, in some embodiments, alterable material 40 may be considered to have one or more inorganic components disbursed in an organic “AZ R”-type composition. However, alterable material 40 may comprise other than organic and other than “AZ R”-type compositions, for example as explained below.

A challenge with the “AZ R” materials is that they can be similar enough in composition to photoresist that it may be difficult to selectively remove photoresist relative to hardened “AZ R” materials. In one embodiment, alterable material 40 may be similar to the “AZ R” materials in that it may comprise a similar or identical organic composition which is altered (for instance, forms cross-links) upon exposure to one or more substances (for instance, acid) released from material 20 over which material 40 lies when the substrate is baked. However, unlike “AZ R” materials, material 40 may also contain one or more components dispersed in the organic composition which are provided to chemically change material 40 relative to material of features 20 (for example, photoresist in embodiments where material of features 20 may be selectively removed relative to material 40 ). Components which may be dispersed in an organic composition of a material 40 may include one or more of titanium, carbon, fluorine, bromine, silicon and germanium. Any carbon dispersed in the organic composition may be part of a carbide compound so it is chemically different from bulk carbon of the organic composition. Any fluorine and/or bromine may be, for example, comprised of hydrofluoric acid and hydrobromic acid. In some embodiments, the components dispersed in an organic composition of a material 40 include one or more inorganic components, such as, for example, silicon, germanium, metals (for instance, titanium, tungsten, platinum, etc.) and/or metal-containing compounds (for instance, metal nitride, metal silicide, etc.). The component of material 40 that is similar to “AZ R” materials may be referred to as an “AZ R”-type composition. Accordingly, in some embodiments, alterable material 40 may be considered to have one or more inorganic components dispersed in an organic “AZ R”-type composition. However, alterable material 40 may comprise other than organic and other than “AZ R”-type compositions, for example as explained below.

Referring to FIG. 18 , substrate 10 b has been subjected to conditions which cause inter-diffusion of materials 20 and 40 proximate spaced second features 20 . Some substance of material 20 alters material 40 to form altered material 44 proximate spaced second features 20 . Accordingly, the alterable material is capable of being altered with material from the spaced second features to form altered material on sidewalls of the spaced second features, for example as shown in FIG. 18 . In one embodiment, the altering alters a portion of the alterable material 40 adjacent each of spaced second features 20 to form altered material 44 while leaving portions of the alterable material distal from spaced second features unaltered. FIG. 18 also depicts an embodiment wherein altered material 44 has been formed elevationally over spaced second features 20 . Altered material 44 may or may not be homogenous.

In some embodiments, material of spaced second features 20 comprises chemically-amplified photoresist, and the substance from such photoresist which imparts the altering of material 40 is acid. The acid may be caused to be released from photoresist by baking semiconductor substrate 10 b at a temperature of at least about 100° C. The acid forms cross-links with “AZ R”-type composition of material 40 . The amount of cross-linking, and the distance that the cross-linking spreads from spaced features 20 may be adjusted by modifying one or both of bake time and bake temperature.

As an additional example where spaced features 20 comprise silicon, an example alterable material 40 is a refractory metal, such as titanium, to result in a reaction ultimately to form the altered material to comprise a metal silicide. Such by way of example only is shown and described in U.S. Patent Application Publication No. US2007/0049030. Additional alterable materials depending at least in part upon the composition of the spaced second features are also of course contemplated, and whether existing or yet-to-be developed.

Referring to FIG. 19 , and in one embodiment, un-reacted distal portions of material 40 (not shown) which were not altered to form material 44 have been removed, for example by etching, selectively relative to altered material 44 . Suitable chemistries and conditions may be selected by the artisan depending upon composition of materials 40 , 44 and 12 . For example with respect to the “AZ R”-type compositions referred to above, such removal may be accomplished utilizing isopropyl alcohol and/or SOLUTION C™ as discussed above. Where material 40 may comprise additional components dispersed in an “AZ R”-type composition, such components may simply rinse away as the non-altered regions of material 40 are removed. Alternately, such additional components may be removed with solvents which remove the additional components. For instance, if silicon dioxide is utilized as a component of material 40 , hydrofluoric acid may be utilized during removal of the non-altered regions of material 40 to ensure that the silicon dioxide of the non-altered regions is removed in addition to the “AZ R”-type composition of the non-altered regions.

Referring to FIG. 20 , second material 24 b has been deposited over altered material 44 , with second material 24 b being of some different composition from that of altered material 44 and from that of spaced second features 20 .

Referring to FIG. 21 , only a portion of second material 24 b has been removed to expose altered material 44 and form spaced second material 30 b.

Referring to FIG. 22 , altered material 44 (not shown) has been etched from between spaced second material 30 b and spaced third features 32 b have been formed which comprise spaced second material 30 b . Third features 32 b are spaced from second features 20 . FIG. 22 depicts a mask pattern 35 b which is used to process substrate 12 there-through, for example by etching and/or ion implanting and/or other processing, whether existing or yet-to-be developed.

Alternate embodiments to that depicted by FIGS. 19-21 are also contemplated. For example, material 40 of FIG. 18 might be processed such that only a portion thereof is removed to expose altered material 44 and form spaced alterable material as opposed to deposition of material 24 b and removing a portion thereof. For example, material 40 of FIG. 18 could be removed to directly produce the construction of FIG. 21 wherein material 24 b is substituted by material 40 . After forming such spaced alterable material, altered material 44 would be etched from between the spaced alterable material and third features would be formed which comprise the spaced alterable material, with the third features being spaced from the second features. For example, the construction of FIG. 22 could be formed wherein material 24 b is substituted by spaced alterable material 40 after material 44 of FIG. 21 has been removed.

Additional embodiments are next described with reference to FIGS. 23-31 with respect to a substrate fragment 10 c . Like numerals from the above-described embodiments have been utilized where appropriate, with construction differences being indicated with the suffix “c” or with different numerals. While the suffix “c” indicates different construction, example material for such constructions is the same as used in the above embodiments for the same numerals without the suffix “c”. Referring to FIG. 23 , spaced first features 16 c have been formed over substrate 12 . An alterable material 40 c has been deposited over spaced first features 16 c.

Referring to FIG. 24 , alterable material 40 c has been altered with material from spaced first features 16 c to form altered material 44 c on sidewalls of spaced first features 16 c . As described above, such altering may occur during deposition of alterable material 40 c and/or after completion of deposition of alterable material 40 c . In one embodiment, no altering occurs until after completion of deposition of alterable material 40 c , for example essentially as depicted in the processing of the substrate of FIG. 23 to that of FIG. 24 .

Referring to FIG. 25 , those portions of the alterable material 40 c (not shown) which were not altered have been removed from substrate 10 c.

Referring to FIG. 26 , altered material 44 c has been anisotropically etched to form second spaced features 20 c.

Referring to FIG. 27 , spaced first features 16 c (not shown) have been removed from the substrate leaving at least part of second spaced features 20 c which comprise altered material 44 c.

Referring to FIG. 28 , a first material 22 c has been deposited over spaced second features 20 c , and which is of some different composition from that of spaced second features 20 c and has a non-planar outermost surface 23 c.

Referring to FIG. 29 , a second material 24 c has been deposited over first material 22 c , with second material 24 c being of some different composition from that of first material 22 c and from that of spaced second features 20 c.

Referring to FIG. 30 , only a portion of second material 24 c has been removed to expose first material 22 c and form spaced second material 30 c.

Referring to FIG. 31 , first material 22 c has been etched from between spaced second material 30 c , and spaced third features 32 c have been formed which comprise spaced second material 24 c . Third features 32 c are spaced from second features 20 c . The FIGS. 23-31 embodiment shows a starting pitch Q in FIG. 23 and a resultant pitch in FIG. 31 of one-fourth of Q (an integer factor of 4). Other multiplication, including non-integer fractional multiplication, may also result depending on thickness of the deposited materials and any laterally trimming of the formed features. Regardless, FIG. 31 depicts an example mask pattern 35 c comprising spaced second features 20 c and spaced third features 32 c through which substrate 12 may be processed, for example as described above.

Additional embodiments are next described with reference to FIGS. 32-37 . FIG. 32 depicts alternate processing with respect to a substrate fragment 10 d in the processing sequence of FIG. 28 . Like numerals from the above-described embodiments have been utilized where appropriate, with construction differences being indicated with the suffix “d” or with different numerals. While the suffix “d” indicates different construction, example material for such constructions is the same as used in the above embodiments for the same numerals without the suffix “d”.

Referring to FIG. 32 , the processing of FIGS. 23-27 has occurred wherein material 40 c of FIG. 23 may be considered as first alterable material which was formed over spaced first features 16 c , and which was altered with material from spaced first features 16 c to form a first altered material 44 c on sidewalls of spaced first features 16 c . Spaced first features 16 c have been removed from the substrate and spaced second features 20 d were formed which comprise first altered material 44 , which is designated as 44 d in FIG. 32 . A second alterable material 60 has been formed over spaced second features 20 d . Composition and attributes of second alterable material 60 are the same as that described above for alterable material 40 and depending at least in part on composition of spaced second features 20 d.

Referring to FIG. 33 , second alterable material 60 has been altered with first altered material 44 d from spaced second features/first altered material 20 d to form second altered material 62 on sidewalls of spaced second features 20 d . Composition and attributes of second altered material 62 are the same as that described above for altered material 44 .

Referring to FIG. 34 , unaltered second alterable material 60 (not shown) has been removed from the substrate selectively relative to second altered material 62 .

Referring to FIG. 35 , a third material 24 d has been formed over second altered material 62 . Third material 24 d is of some different composition from that of second altered material 62 and from that of spaced second features 20 d.

Referring to FIG. 36 , only a portion of third material 24 d has been removed to expose second altered material 62 and form spaced third material 30 d.

Referring to FIG. 37 , second altered material 62 (not shown) has been etched from between spaced third material 30 d , and spaced third features 32 d have been formed which comprise spaced third material 30 d . Third features 32 d are spaced from second features 20 d . Additional lateral and/or vertical trimming may occur relative to the spaced second features and the spaced third features. Regardless, FIG. 37 depicts an example mask pattern 35 d comprising spaced second features 20 d and spaced third features 32 d through which substrate material 12 received elevationally inward of mask pattern 35 d can be processed, for example as described above.

Alternate processing to that depicted by FIGS. 34-37 is also contemplated. For example, second alterable material 60 of FIG. 33 might be processed such that only a portion thereof is removed to expose second altered material 62 and form spaced second alterable material as opposed to deposition of material 24 d and removing a portion thereof. For example, material 60 of FIG. 33 could be removed to directly produce the construction of FIG. 36 wherein material 24 d is substituted by second alterable material 60 . Then, second altered material 62 is etched from between the spaced second alterable material and spaced third features are formed which comprise such spaced second alterable material. For example, the construction of FIG. 37 may be created where second alterable material is substituted for third material 24 d.

In compliance with the statute, the subject matter disclosed herein has been described in language more or less specific as to structural and methodical features. It is to be understood, however, that the claims are not limited to the specific features shown and described, since the means herein disclosed comprise example embodiments. The claims are thus to be afforded full scope as literally worded, and to be appropriately interpreted in accordance with the doctrine of equivalents.