Liquid crystal composition, liquid crystal display element and liquid crystal display

The present disclosure belongs to the field of liquid crystal display, and more particularly relates to a liquid crystal composition and a liquid crystal display element or liquid crystal display comprising the liquid crystal composition.

Early commercial TFT-LCD products basically relate to using a TN display mode, and the largest problem thereof is a narrow viewing angle. With the increase in product size, especially in applications in the TV field, an IPS display mode and a VA display mode, which feature a wide view angle, have been sequentially developed and applied; in particular, on the basis of the improvement of the VA display mode, many big companies have successively made a breakthrough in the development thereof, which mainly depends on the advantages of a wide view angle, a high contrast, no need for rubbing alignment, etc., of the VA mode itself; furthermore, the contrast of the VA mode display is less dependent on the optical anisotropy (Δn) of a liquid crystal, the thickness of a liquid crystal cell (d) and the wavelength (λ) of an incident light, which will inevitably make the VA mode become a very promising display technique.

However, liquid crystal media used for display elements of the VA mode, etc. themselves are not perfect, and compared with positive dielectric anisotropic display elements, they have the disadvantages of a smaller dielectricity, a relatively slow response time, a relatively high drive voltage, etc., and are more prone to the problems of defective displaying, afterimage etc.

At present, liquid crystal compositions which are applicable to display devices and excellent in response speed and in which various display defects are improved are still desired.

In order to solve the problems in the prior art, the present inventors have conducted intensive studies and surprisingly found that a liquid crystal composition containing a combination of a compound represented by formula I, a compound represented by formula II, and a compound represented by formula III as mentioned hereinafter exhibits a fast response speed when applied to a liquid crystal display element; furthermore, when the liquid crystal composition is used in the manufacture procedure for an ODF liquid crystal device, the liquid crystal display has no defective displaying, thereby completing the present disclosure.

A first object of the present disclosure is to provide a liquid crystal composition having a low rotary viscosity (γ1), a larger dielectric anisotropy (Δε), and a fast response speed.

A second object of the present disclosure is to provide a liquid crystal display element comprising the liquid crystal composition of the present disclosure. The liquid crystal display element has a fast response speed.

A third object of the present disclosure is to further provide a liquid crystal display comprising the liquid crystal composition of the present disclosure. The liquid crystal display has a fast response speed.

In order to achieve the above-mentioned objects, the following technical solution is used in the present disclosure:

The liquid crystal composition of the present disclosure comprising a compound represented by formula I, one or more compounds represented by formula II, one or more compounds represented by formula III, and at least one polymerizable compound:

wherein:

in formula II, R 1 and R 2 each independently represent an alkyl group having a carbon atom number of 1-10; and

in formula III, R 3 and R 4 each independently represent an alkyl group having an atom number of 1-10, a fluorine-substituted alkyl group having a carbon atom number of 1-10, an alkoxy group having a carbon atom number of 1-10 or a fluorine-substituted alkoxy group having a carbon atom number of 1-10.

In the liquid crystal composition of the present disclosure, there is no limitation on the above-mentioned polymerizable compound, and a person skilled in the art would be able to select a suitable polymerizable compound according to common knowledge in the art.

The present disclosure further provides a liquid crystal display element comprising the liquid crystal composition of the present disclosure, which liquid crystal display element is an active matrix addressing display element or a passive matrix addressing display element.

The present disclosure further provides a liquid crystal display comprising the liquid crystal composition of the present disclosure, which liquid crystal display is an active matrix addressing display or a passive matrix addressing display.

[Liquid Crystal Composition]

The liquid crystal composition of the present disclosure comprising a compound represented by formula I, one or more compounds represented by formula II, one or more compounds represented by formula III, and at least one polymerizable compound.

wherein:

in formula II, R 1 and R 2 each independently represent an alkyl group having a carbon atom number of 1-10; and

in formula III, R 3 and R 4 each independently represent an alkyl group having an atom number of 1-10, a fluorine-substituted alkyl group having a carbon atom number of 1-10, an alkoxy group having a carbon atom number of 1-10 or a fluorine-substituted alkoxy group having a carbon atom number of 1-10.

In formula II, as the alkyl groups having a carbon atom number of 1-10 as represented by R 1 and R 2 mentioned above, examples include methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, n-pentyl, isopentyl, hexyl, heptyl, octyl, nonyl, decyl, etc.

In formula III, as the alkyl groups having a carbon atom number of 1-10 as represented by R 3 and R 4 mentioned above, examples include methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, n-pentyl, isopentyl, hexyl, heptyl, octyl, nonyl, decyl, etc.

As the alkoxy group having a carbon atom number of 1-10, examples include methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, isobutoxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, nonyloxy, decyloxy etc.

The fluorine substitution as mentioned above may be a monofluoro substitution, a difluoro substitution, a trifluoro substitution, etc., and the fluorine substitution may be a fluorine substitution on a single carbon atom or may also be a fluorine substitution on a plurality of carbon atoms.

As the alkoxy group having a carbon atom number of 1-10, examples include groups obtained by further fluoro-substituting, e.g., monofluoro-substituting, difluoro-substituting or trifluoro-substituting, the alkoxy groups having a carbon atom number of 1-10 as mentioned above, such as methoxy, ethoxy, n-propoxy, isopropoxy, n-butoxy, isobutoxy, pentyloxy, hexyloxy, heptyloxy, octyloxy, nonyloxy and decyloxy.

In the liquid crystal composition of the present disclosure, the above-mentioned polymerizable compound is preferably selected from formulas

The liquid crystal composition of the present disclosure preferably further comprises one or more compounds represented by formula IV:

wherein

R 5 and R 6 each independently represent an alkyl group having a carbon atom number of 1-10, a fluorine-substituted alkyl group having a carbon atom number of 1-10, an alkoxy group having a carbon atom number of 1-10, a fluorine-substituted alkoxy group having a carbon atom number of 1-10, an alkenyl group having a carbon atom number of 2-10, a fluorine-substituted alkenyl group having a carbon atom number of 2-10, an alkenoxy group having a carbon atom number of 3-8 or an fluorine-substituted alkenoxy group having a carbon atom number of 3-8, and any one or more unconnected CH 2 in the groups represented by R 5 and R 6 are optionally substituted with cyclopentyl, cyclobutyl or cyclopropyl;

Z 1 and Z 2 each independently represent a single bond, —CH 2 CH 2 - or —CH 2 O—;

represent 1,4-cyclohexylene, 1,4-cyclohexenylene, 1,4-phenylene or a fluorinated 1,4-phenylene; and

m and n each independently represent 0, 1 or 2, with m+n<2.

In the liquid crystal composition of the present disclosure, preferably, the compound represented by formula IV mentioned above is selected from the group consisting of compounds represented by formula IV-1 to IV-13 below:

wherein:

R 51 and R 61 each independently represent an alkyl group having a carbon atom number of 1-10, a fluorine-substituted alkyl group having a carbon atom number of 1-10, an alkoxy group having a carbon atom number of 1-10, a fluorine-substituted alkoxy group having a carbon atom number of 1-10, an alkenyl group having a carbon atom number of 2-10, a fluorine-substituted alkenyl group having a carbon atom number of 2-10, an alkenoxy group having a carbon atom number of 3-8 or an fluorine-substituted alkenoxy group having a carbon atom number of 3-8, and any one or more unconnected CH 2 in the groups represented by R 51 and R 61 are optionally substituted with cyclopentyl, cyclobutyl or cyclopropyl.

In the liquid crystal composition of the present disclosure, further preferably, the compound represented by formula IV mentioned above is selected from the group consisting of compounds represented by formula IV-2 to IV-5 below:

wherein the above-mentioned liquid crystal compounds have a large dielectric anisotropy, a suitable optical anisotropy, an appropriate rotary viscosity, and an appropriate K value, and may be used for developing a liquid crystal display or liquid crystal display element having negative dielectric anisotropy.

In the liquid crystal composition of the present disclosure, further preferably, the compound represented by formula IV mentioned above is selected from the group consisting of compounds represented by formula IV-2 and IV-3 below:

wherein the above-mentioned liquid crystal compounds have a large K value and a high clearing point, and may be used for developing a liquid crystal composition having a fast response and a wider temperature display range.

In the liquid crystal composition of the present disclosure, further preferably, the compound represented by formula IV mentioned above is selected from the group consisting of compounds represented by formula IV-4 and IV-5 below:

wherin the above-mentioned liquid crystal compounds have such a rotary viscosity γ1 that they can be used for developing a liquid crystal composition having a fast response.

In the liquid crystal composition of the present disclosure, preferably, where the total content of the components other than the polymerizable compound is 100% by mass, the total mass content of the compound represented by formula I above is 1%-65%; the total mass content of the compound represented by formula II above is 1%-15%; the polymerizable compound above is added on the basis of the total mass % of the liquid crystal in an amount of 0.01%-1%, preferably 0.03%-0.4%; and the total mass content of the compound represented by formula III above is 1%-25%.

The liquid crystal composition of the present disclosure preferably further comprises one or more compounds represented by formula V:

wherein,

R 7 and R 8 each independently represent an alkyl group having a carbon atom number of 1-10, a fluorine-substituted alkyl group having a carbon atom number of 1-10, an alkoxy group having a carbon atom number of 1-10, a fluorine-substituted alkoxy group having a carbon atom number of 1-10, an alkenyl group having a carbon atom number of 2-10 or a fluorine-substituted alkenyl group having a carbon atom number of 2-10; and

and each independently represent 1,4-cyclohexylene, 1,4-cyclohexenylene or 1,4-phenylene; furthermore, where

simultaneously represent 1,4-cyclohexylene, and one of R 5 and R 6 represents propyl, the other does not represent vinyl.

In the liquid crystal composition of the present disclosure, preferably, the compound represented by formula V mentioned above is selected from the group consisting of compounds represented by formula V-1 to V-3 below:

wherein,

R 7 and R 8 each independently represent an alkyl group having a carbon atom number of 1-10, a fluorine-substituted alkyl group having a carbon atom number of 1-10, an alkoxy group having a carbon atom number of 1-10, a fluorine-substituted alkoxy group having a carbon atom number of 1-10, an alkenyl group having a carbon atom number of 2-10 or a fluorine-substituted alkenyl group having a carbon atom number of 2-10; and in formula V-1, where one of R 7 and R 8 represents propyl, the other does not represent vinyl.

The liquid crystal composition of the present disclosure preferably further comprises one or more compounds represented by formula VI:

wherein,

R 9 and R 10 each independently represent an alkyl group having a carbon atom number of 1-10, a fluorine-substituted alkyl group having a carbon atom number of 1-10, an alkoxy group having a carbon atom number of 1-10, a fluorine-substituted alkoxy group having a carbon atom number of 1-10, an alkenyl group having a carbon atom number of 2-10 or a fluorine-substituted alkenyl group having a carbon atom number of 2-10; and

each independently represent 1,4-cyclohexylene 1,4-cyclohexenylene or 1,4-phenylene; furthermore, where

represents 1,4-cyclohexylene,

represents 1,4-phenylene, R 9 and R 10 do not simultaneously represent an alkyl group having a carbon atom number of 1-10.

In the liquid crystal composition of the present disclosure, preferably, the compound represented by formula VI mentioned above is selected from the group consisting of compounds represented by formula VI-1 to VI-3 below:

wherein,

R 91 , R 92 , R 93 , R 101 , R 102 and R 103 each independently represent an alkyl group having a carbon atom number of 1-10, a fluorine-substituted alkyl group having a carbon atom number of 1-10, an alkoxy group having a carbon atom number of 1-10, a fluorine-substituted alkoxy group having a carbon atom number of 1-10, an alkenyl group having a carbon atom number of 2-10 or a fluorine-substituted alkenyl group having a carbon atom number of 2-10; furthermore, R 92 and R 102 do not simultaneously represent an alkyl group having a carbon atom number of 1-10.

[Liquid Crystal Display Element]

The liquid crystal display element of the present disclosure comprises the liquid crystal composition of the present disclosure, which liquid crystal display element is an active matrix display element or a passive matrix display element.

Optionally, said liquid crystal display element may be an active matrix liquid crystal display element.

Optionally, said active matrix display element may be, for example, a PSVA-TFT liquid crystal display element.

The liquid crystal display element comprising the liquid crystal composition of the present disclosure has a faster response speed and a smaller cell thickness.

[Liquid Crystal Display]

The liquid crystal display of the present disclosure comprises the liquid crystal composition of the present disclosure, which liquid crystal display is an active matrix display or a passive matrix display.

Optionally, said liquid crystal display may be an active matrix liquid crystal display.

Optionally, said active matrix display may be, for example, a PSVA-TFT liquid crystal display.

The liquid crystal display comprising the liquid crystal composition of the present disclosure has a faster response speed and a smaller cell thickness.

In order to more clearly illustrate the present disclosure, the present disclosure is further described below in conjunction with preferred examples. A person skilled in the art should understand that the content described in detail below is illustrative rather than limiting, and should not limit the scope of protection of the present disclosure.

In this description, unless otherwise specified, percentages are mass percentages, temperatures are in degree Celsius (° C.), and the specific meanings of the other symbols and the test conditions are as follows:

Cp represents the clearing point (° C.) of the liquid crystal measured by a DSC quantitative method;

Δn represents optical anisotropy, n o is the refractive index of an ordinary light, n e is the refractive index of an extraordinary light, with the test conditions being: 25±2° C., 589 nm and using an abbe refractometer for testing;

Δε represents the dielectric anisotropy, Δε=ε // -ε ⊥ , wherein ε // is a dielectric constant parallel to a molecular axis, and ε // is a dielectric constant perpendicular to the molecular axis, the test condition is 25±0.5° C., a 20 micron parallel cell is used, and INSTEC:ALCT-IR1 is used for the test;

γ1 represents a rotary viscosity (mPa·s), with the test conditions being 25±0.5° C., a 20 micron parallel cell, and INSTEC:ALCT-IR1 for testing; and

K11 is twist elastic constant, and K33 is splay elastic constant, with the test conditions being: 25° C., INSTEC:ALCT-IR1, and 18 m vertical cell;

A method for preparing the liquid crystal composition involves: weighing various liquid crystal monomers at a certain ratio and then placing them in a stainless steel beaker; placing the stainless steel beaker containing these liquid crystal monomers on a magnetic stirring instrument for heating and melting; and after the liquid crystal monomers in the stainless steel beaker are mostly melted, adding a magnetic rotor to the stainless steel beaker; uniformly stirring the mixture; and cooling the mixture to room temperature to obtain the liquid crystal composition.

In the examples of the present disclosure, liquid crystal monomer structures are represented by codes, wherein the codes of cyclic structures, end groups and linking groups of liquid crystals are represented as follows in tables 1 and 2.

the code of which is CC-Cp-V1;

the code of which is CPY-2-O2;

the code of which is CCY-3-O2;

the code of which is COY-3-O2;

the code of which is CCOY-3-O2;

and

the code of which is Sc-2O—O4.