A polymer film comprising:na binder resin having a weight average molecular weight of 30,000 to 800,000; anda polyrotaxane including a macrocycle to which a lactone-based compound is bonded, a linear molecule penetrating into the macrocycle, and a blocking group arranged at both ends of the linear molecule to prevent the macrocycle from being separated,wherein a rate of a polyrotaxane in which an end of the lactone-based compound is substituted by a (meth)acrylate-based compound in the entire polyrotaxane is 40 mol % to 70 mol %, andthe polymer film is bent over a mandrel having a diameter of 10 mm or less without cracking in a mandrel test.
›2.↳ 1The polymer film of claim 1, whereinnthe polymer film has sufficient flexibility to be bent over a cylindrical steel mandrel having a diameter of 7.0 …d2
The polymer film of claim 1, whereinnthe polymer film has sufficient flexibility to be bent over a cylindrical steel mandrel having a diameter of 7.0 mm or less without cracking at the time of performing measurement according to ASTM Standard D522-93A method B.
›3.↳ 1The polymer film of claim 1, whereinnthe polymer film has a thickness of 5 μm to 100 μm.d2
The polymer film of claim 1, whereinnthe polymer film has a thickness of 5 μm to 100 μm.
›4.↳ 1The polymer film of claim 1, whereinnelongation measured according to ASTM D638 at room temperature is 5% to 500%.d2
The polymer film of claim 1, whereinnelongation measured according to ASTM D638 at room temperature is 5% to 500%.
›5.↳ 1The polymer film of claim 1, whereinnthe polymer film has light transmittance of 92.0% or more and haze of 0.9 or less.d2
The polymer film of claim 1, whereinnthe polymer film has light transmittance of 92.0% or more and haze of 0.9 or less.
›6.↳ 1The polymer film of claim 1, whereinnthe polymer film is used as a substrate, an external protective film, or a cover window of a light emitting eleme…d2
The polymer film of claim 1, whereinnthe polymer film is used as a substrate, an external protective film, or a cover window of a light emitting element display device.
›7.↳ 1The polymer film of claim 1, whereinnthe polymer film has a glass transition temperature of −80° C. to 100° C.d2
The polymer film of claim 1, whereinnthe polymer film has a glass transition temperature of −80° C. to 100° C.
›8.↳ 1The polymer film of claim 1, whereinnthe binder resin includes at least one selected from a group consisting of a (meth)acrylate-based polymer, a uret…d2
The polymer film of claim 1, whereinnthe binder resin includes at least one selected from a group consisting of a (meth)acrylate-based polymer, a urethane (meth)acrylate-based polymer, a polyurethane resin, and a silicone-epoxy copolymer having a (meth)acrylate group introduced at an end thereof.
›9.↳ 1The polymer film of claim 1, whereinnthe macrocycle includes at least one selected from a group consisting of α-cyclodextrin, β-cyclodextrin, and γ-cy…d2
The polymer film of claim 1, whereinnthe macrocycle includes at least one selected from a group consisting of α-cyclodextrin, β-cyclodextrin, and γ-cyclodextrin.
›10.↳ 1The polymer film of claim 1, whereinnthe lactone-based compound is directly bonded to the macrocycle or bonded to the macrocycle via a straight or bra…d2
The polymer film of claim 1, whereinnthe lactone-based compound is directly bonded to the macrocycle or bonded to the macrocycle via a straight or branched oxyalkylene group having 1 to 10 carbon atoms.
›11.↳ 1The polymer film of claim 1, whereinna residue of the lactone-based compound includes a functional group of the following Chemical Formula 1:d2
The polymer film of claim 1, whereinna residue of the lactone-based compound includes a functional group of the following Chemical Formula 1:
›12.↳ 1The polymer film of claim 1, whereinnthe (meth)acrylate-based compound is directly bonded to the end of the lactone-based compound or bonded to the en…d2
The polymer film of claim 1, whereinnthe (meth)acrylate-based compound is directly bonded to the end of the lactone-based compound or bonded to the end of the lactone-based compound via a urethane bond, an ether bond, a thioester bond, or an ester bond.
›13.↳ 1The polymer film of claim 1, whereinna residue of the (meth)acrylate-based compound bonded to the end of the lactone-based compound includes a functio…d2
The polymer film of claim 1, whereinna residue of the (meth)acrylate-based compound bonded to the end of the lactone-based compound includes a functional group of the following Chemical Formula 2:
›14.↳ 1The polymer film of claim 1, whereinnthe linear molecule is a polyoxyalkylene-based compound or a polylactone-based compound.d2
The polymer film of claim 1, whereinnthe linear molecule is a polyoxyalkylene-based compound or a polylactone-based compound.
›15.↳ 1The polymer film of claim 1, whereinnthe linear molecule has a weight average molecular weight of 1000 to 50,000.d2
The polymer film of claim 1, whereinnthe linear molecule has a weight average molecular weight of 1000 to 50,000.
›16.↳ 1The polymer film of claim 1, whereinnthe blocking group includes at least one functional group selected from a group consisting of a dinitrophenyl gro…d2
The polymer film of claim 1, whereinnthe blocking group includes at least one functional group selected from a group consisting of a dinitrophenyl group, a cyclodextrin group, an adamantane group, a trityl group, a fluorescein group, and a pyrene group.
›17.↳ 1The polymer film of claim 1, whereinnthe polyrotaxane has a weight average molecular weight of 100,000 to 800,000.d2
The polymer film of claim 1, whereinnthe polyrotaxane has a weight average molecular weight of 100,000 to 800,000.
›18.↳ 1The polymer film of claim 1, whereinnthe polymer film contains the polyrotaxane at a content of 1 wt % to 50 wt % based on the entire weight of the po…d2
The polymer film of claim 1, whereinnthe polymer film contains the polyrotaxane at a content of 1 wt % to 50 wt % based on the entire weight of the polymer film.
›19.↳ 1The polymer film of claim 1, whereinnthe polymer film has a crosslinked structure between the binder resin and the polyrotaxane.d2
The polymer film of claim 1, whereinnthe polymer film has a crosslinked structure between the binder resin and the polyrotaxane.
›20.↳ 1The polymer film of claim 1, whereinnthe polymer film contains a multifunctional acrylate-based compound forming a crosslink bond with at least one of…d2
The polymer film of claim 1, whereinnthe polymer film contains a multifunctional acrylate-based compound forming a crosslink bond with at least one of the binder resin and the polyrotaxane.
›21.↳ 1A flexible light emitting element display device comprising the polymer film of claim 1.d2+2
A flexible light emitting element display device comprising the polymer film of claim 1.
›22.↳ 21The flexible light emitting element display device of claim 21, wherein the flexible light emitting element display device includes the polymer film a…d3
The flexible light emitting element display device of claim 21, wherein the flexible light emitting element display device includes the polymer film as a substrate, an external protective film, or a cover window.
›23.↳ 21The flexible light emitting element display device of claim 21, wherein the flexible light emitting element display device includes a cathode providin…d3
The flexible light emitting element display device of claim 21, wherein the flexible light emitting element display device includes a cathode providing electrons, an electron transport layer, an emission layer, a hole transport layer, and an anode providing holes, andnthe polymer film is bonded to at least one surface of the cathode or the anode.
›24.↳ 1A rollable display device comprising the polymer film of claim 1.d2+1
A rollable display device comprising the polymer film of claim 1.
›25.↳ 24The rollable display device of claim 24, wherein the rollable display device includes the polymer film as a substrate, an external protective film, or…d3
The rollable display device of claim 24, wherein the rollable display device includes the polymer film as a substrate, an external protective film, or a cover window.