A modified rubber masterbatch, consisting of an uncrosslinked rubber and rubber particles having radiation crosslinked structure dispersed therein, wherein the rubber particles having radiation crosslinked structure are synthetic rubber particles and/or natural rubber particles with an average particle size of 20 to 500 nm, and a gel content of 60% by weight or higher, and the uncrosslinked rubber is a styrene-butadiene rubber; and wherein the weight ratio of the rubber particles having radiation crosslinked structure to the uncrosslinked rubber is greater than 20:80 and less than or equal to 80:20.
›2.↳ 1The modified rubber masterbatch according to claim 1, characterized in that the rubber particles having radiation crosslinked structure are one or mor…d2
The modified rubber masterbatch according to claim 1, characterized in that the rubber particles having radiation crosslinked structure are one or more selected from the group consisting of natural rubber particles, styrene-butadiene rubber particles, carboxylated styrene-butadiene rubber particles, nitrile butadiene rubber particles, carboxylated nitrile butadiene rubber particles, chloroprene rubber particles, polybutadiene rubber particles, silicone rubber particles, acrylic rubber particles, and styrene-butadiene-vinylpyridine rubber particles.
›3.↳ 1The modified rubber masterbatch according to claim 1, characterized in that the rubber particles having radiation crosslinked structure are of homogen…d2
The modified rubber masterbatch according to claim 1, characterized in that the rubber particles having radiation crosslinked structure are of homogeneous structure.
›4.↳ 1The modified rubber masterbatch according to claim 1, characterized in that the weight ratio of the rubber particles having radiation crosslinked stru…d2
The modified rubber masterbatch according to claim 1, characterized in that the weight ratio of the rubber particles having radiation crosslinked structure to the uncrosslinked rubber is 30:70-80:20.
›5.↳ 1The modified rubber masterbatch according to claim 1, characterized in that the modified rubber masterbatch is obtained by mixing the components compr…d2
The modified rubber masterbatch according to claim 1, characterized in that the modified rubber masterbatch is obtained by mixing the components comprising the uncrosslinked rubber latex and a latex of the rubber particles having radiation crosslinked structure till homogeneous and then coagulating them, wherein the latex of the rubber particles having radiation crosslinked structure is a rubber latex obtained by radiation crosslinking.
›6.↳ 1A preparation process for the modified rubber masterbatch according to claim 1, comprising the following steps:n(1) subjecting a latex of synthetic ru…d2+4
A preparation process for the modified rubber masterbatch according to claim 1, comprising the following steps:n(1) subjecting a latex of synthetic rubber and/or natural rubber to the radiation crosslinking and thereby providing the synthetic rubber and/or natural rubber particles in the latex with a crosslinked structure, the said gel content and meanwhile an average particle size fixed in the said average particle size range;(2) mixing till homogeneous the above radiation crosslinked latex of the synthetic rubber and/or natural rubber with a latex of the uncrosslinked rubber according to the said weight ratio of the rubber particles having radiation crosslinked structure to the uncrosslinked rubber;(3) coagulating the above mixed latices to obtain the said modified rubber masterbatch.
›7.↳ 6The preparation process according to claim 6, characterized in that the latex of synthetic rubber and/or natural rubber latex is one or more selected …d3
The preparation process according to claim 6, characterized in that the latex of synthetic rubber and/or natural rubber latex is one or more selected from the group consisting of natural rubber latex, styrene-butadiene rubber latex, carboxylated styrene-butadiene rubber latex, nitrile butadiene rubber latex, carboxylated nitrile butadiene rubber latex, chloroprene rubber latex, polybutadiene rubber latex, silicone rubber latex or acrylic rubber latex, styrene-butadiene-vinylpyridine rubber latex and the like.
›20.↳ 6The preparation process according to claim 6, characterized in that the latex of synthetic rubber and/or natural rubber latex is one or more selected …d3+2
The preparation process according to claim 6, characterized in that the latex of synthetic rubber and/or natural rubber latex is one or more selected from the group consisting of nitrile butadiene rubber latex, styrene-butadiene-vinylpyridine rubber latex, styrene-butadiene rubber latex, and carboxylated styrene-butadiene rubber latex.
›21.↳ 20The preparation process according to claim 20, characterized in that the latex of synthetic rubber and/or natural rubber latex is one or more selected…d4+1
The preparation process according to claim 20, characterized in that the latex of synthetic rubber and/or natural rubber latex is one or more selected from the group consisting of styrene-butadiene-vinylpyridine rubber latex and nitrile butadiene rubber latex.
›22.↳ 21The preparation process according to claim 21, characterized in that the latex of synthetic rubber and/or natural rubber latex is nitrile butadiene ru…d5
The preparation process according to claim 21, characterized in that the latex of synthetic rubber and/or natural rubber latex is nitrile butadiene rubber latex.
›8.↳ 1A rubber composition, comprising a blend of the modified rubber masterbatch according to claim 1 and a base rubber, wherein the modified rubber master…d2+8
A rubber composition, comprising a blend of the modified rubber masterbatch according to claim 1 and a base rubber, wherein the modified rubber masterbatch is present in an amount of 1 to 70 parts by weight, relative to per 100 parts by weight of the base rubber.
›9.↳ 8The rubber composition according to claim 8, characterized in that the base rubber is one or more selected from the group consisting of natural rubber…d3
The rubber composition according to claim 8, characterized in that the base rubber is one or more selected from the group consisting of natural rubber, modified natural rubber, and synthetic rubber.
›10.↳ 8A preparation process for the rubber composition according to claim 8, comprising a step of compounding the modified rubber masterbatch and the base r…d3+1
A preparation process for the rubber composition according to claim 8, comprising a step of compounding the modified rubber masterbatch and the base rubber in the said amounts to obtain a rubber composition.
›11.↳ 10The preparation process according to claim 10, characterized in that the preparation process for the modified rubber masterbatch comprising the follow…d4
The preparation process according to claim 10, characterized in that the preparation process for the modified rubber masterbatch comprising the following steps:n(1) subjecting a latex of synthetic rubber and/or natural rubber to the radiation crosslinking and thereby providing the synthetic rubber and/or natural rubber particles in the latex with a crosslinked structure, the said gel content and meanwhile an average particle size fixed in the said average particle size range;(2) mixing till homogeneous the above radiation crosslinked latex of the synthetic rubber and/or natural rubber with a latex of the uncrosslinked rubber according to the said weight ratio of the rubber particles having radiation crosslinked structure to the uncrosslinked rubber;(3) coagulating the above mixed latices to obtain the said modified rubber masterbatch.
›12.↳ 8A vulcanized rubber produced from the rubber composition according to claim 8.d3
A vulcanized rubber produced from the rubber composition according to claim 8.
›23.↳ 8The rubber composition of claim 8, wherein the modified rubber masterbatch is present in an amount of 1 to 40 parts by weight relative to per 100 part…d3+1
The rubber composition of claim 8, wherein the modified rubber masterbatch is present in an amount of 1 to 40 parts by weight relative to per 100 parts by weight of the base rubber.
›24.↳ 23The rubber composition of claim 23, wherein the modified rubber masterbatch is present in an amount of 1 to 30 parts by weight relative to per 100 par…d4
The rubber composition of claim 23, wherein the modified rubber masterbatch is present in an amount of 1 to 30 parts by weight relative to per 100 parts by weight of the base rubber.
›25.↳ 8The rubber composition of claim 8, characterized in that the base rubber is one or more selected from the group consisting of natural rubber, solution…d3+1
The rubber composition of claim 8, characterized in that the base rubber is one or more selected from the group consisting of natural rubber, solution polymerized styrene-butadiene rubber or its oil extended products, emulsion polymerized styrene-butadiene rubber or its oil extended products, and polybutadiene rubber or its oil extended products.
›26.↳ 25The rubber composition of claim 25, characterized in that the base rubber is one or more selected from the group consisting of solution polymerized st…d4
The rubber composition of claim 25, characterized in that the base rubber is one or more selected from the group consisting of solution polymerized styrene-butadiene rubber or its oil extended products, emulsion polymerized styrene-butadiene rubber or its oil extended products, and polybutadiene rubber or its oil extended products.
›13.↳ 1The modified rubber masterbatch according to claim 1, wherein the rubber particles having radiation crosslinked structure are synthetic rubber particl…d2+1
The modified rubber masterbatch according to claim 1, wherein the rubber particles having radiation crosslinked structure are synthetic rubber particles and/or natural rubber particles with an average particle size of 50 to 200 nm.
›14.↳ 13The modified rubber masterbatch according to claim 13, wherein the rubber particles having radiation crosslinked structure are synthetic rubber partic…d3
The modified rubber masterbatch according to claim 13, wherein the rubber particles having radiation crosslinked structure are synthetic rubber particles and/or natural rubber particles with an average particle size of 70 to 200 nm.
›15.↳ 1The modified rubber masterbatch according to claim 1, wherein the rubber particles having radiation crosslinked structure are synthetic rubber particl…d2
The modified rubber masterbatch according to claim 1, wherein the rubber particles having radiation crosslinked structure are synthetic rubber particles and/or natural rubber particles with a gel content of 75% by weight or higher.
›16.↳ 1The modified rubber masterbatch according to claim 1, characterized in that the rubber particles having radiation crosslinked structure are one or mor…d2
The modified rubber masterbatch according to claim 1, characterized in that the rubber particles having radiation crosslinked structure are one or more selected from the group consisting of nitrile butadiene rubber particles, styrene-butadiene-vinylpyridine rubber particles, styrene-butadiene rubber particles, and carboxylated styrene-butadiene rubber particles.
›17.↳ 1The modified rubber masterbatch according to claim 1, characterized in that the rubber particles having radiation crosslinked structure are one or mor…d2
The modified rubber masterbatch according to claim 1, characterized in that the rubber particles having radiation crosslinked structure are one or more selected from the group consisting of styrene-butadiene-vinylpyridine rubber particles and nitrile butadiene rubber particles.
›18.↳ 1The modified rubber masterbatch according to claim 1, characterized in that the rubber particles having radiation crosslinked structure nitrile butadi…d2
The modified rubber masterbatch according to claim 1, characterized in that the rubber particles having radiation crosslinked structure nitrile butadiene rubber particles.
›19.↳ 1The modified rubber masterbatch according to claim 1, characterized in that the weight ratio of the rubber particles having radiation crosslinked stru…d2
The modified rubber masterbatch according to claim 1, characterized in that the weight ratio of the rubber particles having radiation crosslinked structure to the uncrosslinked rubber is 40:60-80:20.