Extended-rod benzobisazole polymers

Synthesis of 1H-pyrazole-3,5-dicarbonyl Dichloride

10.0 g of 3,5-pyrazoledicarboxylic acid monohydrate was heated to reflux with 1 liter of thionyl chloride for about three hours under nitrogen, when a nearly homogeneous solution was obtained. After hot filtration and removal of thionyl chloride, an off-white solid, with an m.p. of 89-91° C. was obtained. The solid was recrystallized from hot heptane after charcoal treatment to obtain white, glistening crystals, m.p. 93-94° C., yield 45%, based on the first crop of crystals. IR spectrum: (1765 cm −1 , carbonyl); mass spectrum: (m/e 192, 194, 196 for M, M+2 and M+4 ions); microanalytical results: (calculated, C, 31.13, H, 1.04, N, 14.52, Cl, 36.75), (found, C, 31.17, H, 0.92, N, 14.48, Cl, 36.81).

Synthesis of Polymer I

Into the bottom of a resin flask equipped with a high torque mechanical stirrer, a nitrogen inlet/outlet adapter, and a side opening for additions, were placed 3.4822 g (20 mmole) of 3,5-pyrazole dicarboxylic acid monohydrate, 4.9040 g (20 mmole) of 2,5-diamino-1,4-benzenedithiol dihydrochloride, and 19.96 g of 77% polyphosphoric acid (PPA). The monomers were incorporated into PPA by stirring at room temperature for 2 hours. The resultant mixture was dehydrochlorinated under N 2 flow and heated slowly to 95° C. in an oil bath, and maintained at that temperature for 24 hours. The reaction mixture was cooled to 50° C. and 15.83 g of phosphorus pentoxide was added to the mixture, thus bringing the final polymer concentration to 12%. The mixture was heated under a dry nitrogen flow at 60° C. for 2 hr, 100° C. for 4 hr, and finally at 180° C. for 24 hr. At the end of the polymerization, the viscous polymer dope was precipitated into water. The resultant fibrous polymer was chopped in a Waring blender, collected by suction filtration, washed with ammonium hydroxide, then soxhlet extracted with water for 24 hours, and finally dried under reduced pressure (0.002 torr) at 100° C. for 24 hours. The polymer yield was 5.12 g, an intrinsic viscosity of 7.9 dl/g was measured in methanesulfonic acid at 300° C.

Synthesis of Polymer II

Into the bottom of a resin flask equipped with a high torque mechanical stirrer, a nitrogen inlet/outlet adapter, and a side opening for additions, were placed 3.4822 g (20 mmole) of 3,5-pyrazole dicarboxylic acid monohydrate, 4.2612 g (20 mmole) of 4,6-diaminoresorcinol dihydrochloride, and 23.55 g of 77% polyphosphoric acid (PPA). The monomers were incorporated into PPA by stirring at room temperature for 2 hr. The resultant mixture was dehydrochlorinated under N 2 flow and heated slowly to 100° C. in an oil bath, and maintained at that temperature for 24 hours. The reaction mixture was cooled to 50° C. and 15.35 g of phosphorus pentoxide was added to the mixture, thus bringing the final polymer concentration to 10%. The mixture was heated under a dry nitrogen flow at 60° C. for 2 hr, 100° C. for 4 hr, and finally at 180° C. for 24 hr. At the end of the polymerization, the viscous polymer dope was precipitated into water. The resultant fibrous polymer was chopped in a Waring blender, collected by suction filtration, washed with ammonium hydroxide, then soxhlet extracted with water for 24 hr, and finally dried under reduced pressure (0.002 torr) at 100° C. for 24 hr. The polymer yield was 4.40 g, and intrinsic viscosity of 3.9 dl/g was measured in methanesulfonic acid at 30° C.

Synthesis of Polymer III

Into the bottom of a resin flask equipped with a high torque mechanical stirrer, a nitrogen inlet/outlet adapter, and a side opening for additions, were placed 3.8591 g (20 mmole) of 3,5-pyrazole dicarboxylic acid chloride, 4.2612 g (20 mmole) of 4,6-diaminoresorcinol dihydrochloride, and 17.21 g of 77% polyphosphoric acid (PPA). The monomers were incorporated into PPA by stirring at room temperature for 2 hr. The resultant mixture was dehydrochlorinated under N 2 flow and heated slowly to 100° C. in an oil bath, and maintained at that temperature for 24 hours. The reaction mixture was cooled to 50° C. and 9.59 g of phosphorus pentoxide was added to the mixture, thus bringing the final polymer concentration to 14%. The mixture was heated under a dry nitrogen flow at 600° C. for 2 hr, 100° C. for 4 hr, and finally at 180° C. for 24 hr. At the end of the polymerization, the viscous polymer dope was precipitated into water. The resultant fibrous polymer was chopped in a Waring blender, collected by suction filtration, washed with ammonium hydroxide, then soxhlet extracted with water for 24 hr, and finally dried under reduced pressure (0.002 torr) at 100° C. for 24 hr. The polymer yield was 4.30 g, an intrinsic viscosity of 4.1 dl/g was measured in methanesulfonic acid at 300° C.

Synthesis of Polymer IV

Into the bottom of a resin flask equipped with a high torque mechanical stirrer, a nitrogen inlet/outlet adapter, and a side opening for additions, were placed 1.7411 g (10 mmole) of 3,5-pyrazole dicarboxylic acid monohydrate, 2.8402 g (10 mmole) of 1,2,4,5-tetraaminobenzene tetrahydrochloride, and 10.87 g of 77% polyphosphoric acid (PPA). The monomers were incorporated into PPA by stirring at room temperature for 2 hr. The resultant mixture was dehydrochlorinated under N 2 flow and heated slowly to 100° C. in an oil bath, and maintained at that temperature for 24 hours. The reaction mixture was cooled to 50° C. and 8.23 g of phosphorus pentoxide was added to the mixture, thus bringing the final polymer concentration to 10%. The mixture was heated under a dry nitrogen flow at 60° C. for 2 hr, 100° C. for 4 hr, and finally at 180° C. for 24 hr. At the end of the polymerization, the viscous polymer dope was precipitated into water. The resultant fibrous polymer was chopped in a Waring blender, collected by suction filtration, washed with ammonium hydroxide, then soxhlet extracted with water for 24 hr, and finally dried under reduced pressure (0.002 torr) at 100° C. for 24 hr. The polymer yield was 2.19 g, an intrinsic viscosity of 1.8 dug was measured in methanesulfonic acid at 30° C.

Synthesis of Polymer V

Into the bottom of a resin flask equipped with a high torque mechanical stirrer, a nitrogen inlet/outlet adapter, and a side opening for additions, were placed 1.9299 g (10 mmole) of 3,5-pyrazole dicarboxylic acid chloride, 2.8402 g (10 mmole) of 1,2,4,5-tetraaminobenzene tetrahydrochloride, and 11.17 g of 77% polyphosphoric acid (PPA). The monomers were incorporated into PPA by stirring at room temperature for 2 hr. The resultant mixture was dehydrochlorinated under N 2 flow and heated slowly to 100° C. in an oil bath, and maintained at that temperature for 24 hours. The reaction mixture was cooled to 50° C. and 8.46 g of phosphorus pentoxide was added to the mixture, thus bringing the final polymer concentration to 10%. The mixture was heated under a dry nitrogen flow at 60° C. for 2 hr, 100° C. for 4 hr, and finally at 180° C. for 24 hr. At the end of the polymerization, the viscous polymer dope was precipitated into water. The resultant fibrous polymer was chopped in a Waring blender, collected by suction filtration, washed with ammonium hydroxide, then soxhlet extracted with water for 24 hr, and finally dried under reduced pressure (0.002 torr) at 100° C. for 24 hr. The polymer yield was 2.20 g, an intrinsic viscosity of 3.1 dl/g was measured in methanesulfonic acid at 30° C.

Synthesis of Polymer VI

Into the bottom of a resin flask equipped with a high torque mechanical stirrer, a nitrogen inlet/outlet adapter, and a side opening for additions, were placed 1.9299 g (10 mmole) of 3,5-pyrazole dicarboxylic acid chloride, 2.6656 g (10 mmole) of 2,3,5,6-tetraaminopyridine trihydrochloride monohydrate, and 12.50 g of 77% polyphosphoric acid (PPA). The monomers were incorporated into PPA by stirring at room temperature for 2 hr. The resultant mixture was dehydrochlorinated under N 2 flow and heated slowly to 100° C. in an oil bath, and maintained at that temperature for 24 hours. The reaction mixture was cooled to 50° C. and 7.05 g of phosphorus pentoxide was added to the mixture, thus bringing the final polymer concentration to 10%. The mixture was heated under a dry nitrogen flow at 60° C. for 2 hr, 100° C. for 4 hr, and finally at 180° C. for 24 hr. At the end of the polymerization, the viscous polymer dope was precipitated into water. The resultant fibrous polymer was chopped in a Waring blender, collected by suction filtration, washed with ammonium hydroxide, then soxhlet extracted with water for 24 hr, and finally dried under reduced pressure (0.002 torr) at 100° C. for 24 hr. The polymer yield was 2.21 g, an intrinsic viscosity of 2.6 dl/g was measured in methanesulfonic acid at 30° C.

Having thus described exemplary embodiments of the present invention, it should be noted by those skilled in the art that the disclosures herein are exemplary only and that alternatives, adaptations and modifications may be made within the scope of the present invention.